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The following Chinese herbal formula(s) can treat or relief Headache:

Chinese Formula Actions Indications Symptoms related to headache
Wu Ling San
Five-Ingredient Powder with Poria; Poria Five Powder; Hoelen 5 Powder; Five "Ling" Powder
Diuretic; Tonifies the Spleen; Warms Yang.   1) Water buildup, a greater Yang-stage disorder in which the pathogenic influences have not been released from the Exterior, but have penetrated to the greater Yang organ, the Bladder. 2) Water and Dampness are not properly transformed by the Spleen and transported to the Bladder. The effects of the Spleen's failure to transform and transport Water may be felt throughout the Triple Burner. 3) Retention of congested fluids in the Lower Burner obstructing the Pure Yang.  Acute gastroenteritis; Breathlessness; Cholera; Cough; Diarrhea; Dizziness; Dysuria; Fever; Great thirst due to inappropriate sweating (vomiting soon after drinking); Headache; Oedema; Oliguria; Sensation of heaviness; Throbbing sensations below umbilicus; Urinary tract infection; Vomiting; Vomiting, expectoration of foamy saliva; Ascites (cirrhosis of liver); Chronic nephritis; Cirrhosis; Hydrocele; Ménière's disease; Tongue with a white-greasy coating; Tongue with a white-slippery coating; Floating pulse (Fu); Slippery-Wiry pulse (Hua Xian); Soft pulse (Ru).  
Cong Chi Tang
Scallion and Prepared Soybean Decoction
Releases the Exterior without damaging the Body Fluids; Unblocks Yang Qi and supports the Defensive-Qi; Slightly promotes sweating.   First stage of an externally-contracted Wind-Cold or Wind-Heat disorder.  Headache; Nasal congestion; Aversion to wind; Cold intolerance; Pink tongue, thin-white coating; Floating pulse (Fu); Floating-Tight pulse (Fu Jin).  
Huo Ren Cong Chi Tang
Scallion and Prepared Soybean Decoction
Releases the Exterior; Promotes sweating; Calms pain.   First stage of an externally-contracted Wind-Cold.  Back pain; Headache; Pain in the lower back; Painful neck; Pink tongue, thin-white coating; Floating-Tight pulse (Fu Jin).  

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