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The following Chinese herbal formula(s) can treat or relief Frontal headache:

Chinese Formula Actions Indications Symptoms related to frontal headache
Cang Er Zi San
Xanthium Powder
Releases the Exterior; Calms pain; Unblocks the nose.   Profuse rhinorrhea caused by Wind-Heat attacking the head.  Acute rhinitis; Acute sinusitis; Allergic rhinitis; Allergic sinusitis; Chronic rhinitis; Chronic sinusitis; Frontal headache; Nasal congestion; Profuse rhinorrhea; Purulent rhinorrhea; Thick rhinorrhea; Restlessness; Red tongue, white or yellow coating; Floating-Rapid pulse (Fu Shu).  
Xin Yi Qing Fei Tang
Magnolia Flower Decoction to Clear the Lung
Clears Lung-Heat; Unblocks respiratory tract.   Lung-Heat.  Bronchitis; Fever; Nasal congestion; Nasal polyp; Rhinitis; Sinusitis; Frontal headache; Gastralgia; Yellowish rhinorrhea; Red tongue, thin-white coating; Rapid pulse (Shu).  
Yu Nu Jian
Jade Woman Decoction
Clears Stomach-Heat; Drains Stomach-Heat; Nourishes Yin.   Stomach-Heat with Yin Deficiency due to vigorous Stomach-Fire injuring the Kidney-Yin.  Desire to drink cold drinks; Gingivitis; Loose teeth; Stomatitis; Toothache; Fever; Frontal headache; Irritability; Scarlet red, dry tongue with a Yellow coating; Floating-Slippery-Large-Empty pulse (Fu Hua Da Xu).  

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